A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands.

نویسندگان

  • Yuji Kikukawa
  • Yoshiyuki Kuroda
  • Kosuke Suzuki
  • Mitsuhiro Hibino
  • Kazuya Yamaguchi
  • Noritaka Mizuno
چکیده

By the reaction of TBA(4)H(4)[γ-SiW(10)O(36)] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag(6)](4+) cluster, TBA(8)[Ag(6)(γ-H(2)SiW(10)O(36))(2)]·5H(2)O, could be synthesized, and the molecular structure was determined.

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عنوان ژورنال:
  • Chemical communications

دوره 49 4  شماره 

صفحات  -

تاریخ انتشار 2013